That’s because he rushed into a trap…in the aptly titled “Spin Rushes In”.
“Spin” is Miles’ nickname, btw. Peter’s is “Spidey” and Gwen’s is “Ghost-Spider” (or “Ghosty” for short).
So far the villains include Green Goblin, Rhino and Doc Ock while the supporting heroes include Black Panther, Hulk and Ms. Marvel; I hope we’ll get to see other heroes or villains at least once throughout the series’ run. Maybe a one-hour (two-part) special involving Thanos? (And no, Thanos wouldn’t be committing mass murder, this is a preschool show after all)